Rhonda Rompola took over the program as head coach to begin the 1991-92 season and ushered in a new era for the Mustangs. That season, she led SMU to its first SWC playoff victory, defeating Texas A&M 85-77 in the first round and would be a catalyst for what was to come. Suzanne McAnally, 1989-92 finished her career with a program record 489 assists, helping SMU achieve the feat.
Capitalizing off the momentum from the previous season SMU recorded its first 20-win season as the team finished with a record of 20-10 and was the 1993 National Women’s Invitational Tournament runner-up after falling in the championship game to Arkansas State.
During the 1993-94 season, the program took another step forward and made its first NCAA tournament appearance in school history. It marked the first of three straight tournament appearances for the Mustangs. At the 1995 NCAA Tournament SMU defeated Southern Miss 96-95 in overtime for its first NCAA tournament Victory.
SMU closed out the 90s with two more NCAA Appearances. Arguably, SMU’s greatest post-season run occurred in 1999 as the Mustangs knocked off No. 4-ranked Colorado State to win the WAC Tournament, the program's first conference tournament championship, then defeated No. 25-ranked Toledo in the first round of the NCAA Tournament. SMU ended the season winning eight of its last nine games.
The Mustangs made five NCAA Tournament appearances and won 20 or more games four times in the 90’s. The era featured some of the Mustangs' most prolific offensive attacks as this era produced nine 1,000-point scorers, highlighted by SMU Hall of Famer Karlin Kennedy (1996-00), who totaled 1,785 points over her career, second all-time in school history. She was a three-time All-WAC first team selection and was the 2000 WAC Player of the Year.
Other notable players from the era include Kerri Delany, 1992-96 (1,503 pts- 4th all-time), Shanell Thomas, 1989-93 (1,480 pts – 5th all-time), Kim Brandl, 1994-97 (1,458 pts – 6th all-time), Claudia Brassard, 1995-99 (1,358 pts – 9th all-time) and Jennifer McLaughlin, 1993-96 (1,353 pts -10th all time).